XLSB XML
Not possible

Convert XLSB to XML

Can you convert XLSB to XML?
QUICK ANSWER
Is it possible to convert XLSB to XML?
No - not a direct conversion.

Open the .xlsb file in Microsoft Excel or LibreOffice Calc and save as .xlsx - XLSX is already a ZIP of XML parts and is the correct modern equivalent. For plain tabular data, export to .csv instead.

No direct path
Also to XML: IEPD · XHTML · TSI

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Tested on macOS, Windows & Linux
Last verified Sep 2026

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Why convert XLSB to XML?

XLSB stores worksheet data as binary BIFF12 records inside a ZIP package. The XML Spreadsheet 2003 target (SpreadsheetML) was introduced in Excel 2002 and abandoned when .xlsx arrived in Excel 2007; it cannot represent pivot tables, charts, or conditional formatting from modern Excel, and no current tool or pipeline accepts it.

How to convert XLSB to XML

LibreOffice Calc OPEN-SOURCE

Open the .xlsb file in LibreOffice Calc and use File > Save As to export as .xlsx or .csv.

Apache OpenOffice Calc (OpenOffice.org Calc) FREE

Open the .xlsb file in OpenOffice Calc and use File > Save As to export as .ods or .csv.

Programs that convert XLSB

Microsoft Excel
Apache OpenOffice Calc (OpenOffice.org Calc)
LibreOffice Calc

About these formats

Quality & what to watch

  • XML Spreadsheet 2003 cannot represent modern Excel features such as pivot tables, charts, or structured references - content using these is silently lost.
  • XLSX is already the XML form of an Excel workbook; saving as .xlsx is the complete answer if an XML-based format is the goal.
  • Renaming an .xlsb file to .xml produces an unreadable file - XLSB starts with ZIP magic bytes, not an XML declaration.

Frequently asked questions

I need XLSB data in XML for a script or API - what format should I use?
Export to CSV for raw data or to XLSX if the target system can parse OOXML. A custom XML schema requires a custom script reading the XLSB via XLSX, not Excel's old SpreadsheetML.
Can I just rename the XLSB file to .xml?
No - XLSB is a binary ZIP/OPC package, and renaming it produces a file no XML parser can read.
Does LibreOffice Calc support XLSB files?
Yes - LibreOffice Calc can open XLSB files and save to XLSX or CSV, which are the practical alternatives to the obsolete XML Spreadsheet 2003 format.